Hafnium

Hafnium (Hf)

Hafnium is the 72nd element in the periodic table and has a symbol of Hf and atomic number of 72. It has an atomic weight of 178.49 and a mass number of 180. Hafnium has seventy-two protons and one hundred eight neutrons in its nucleus, and seventy-two electrons in six shells. It is located in group four, period six and block d of the periodic table. Silvery lustrous metallic transition element. Used in tungsten alloys in filaments and electrodes, also acts as a neutron absorber. First reported by Urbain in 1911, existence was finally established in 1923 by D. Coster, G.C. de Hevesy in 1923.
Atomic Number72
Atomic Weight178.49
Mass Number180
Group4
Period6
Blockd
Protons72 p+
Neutrons108 n0
Electrons72 e-
Animated Bohr Model of Hf (Hafnium)

Physical Properties

Atomic Radius
Molar Volume
Covalent Radius
Metallic Radius
Ionic Radius
Crystal Radius
Van der Waals Radius
Density
Atomic Radii of the Elements: Hafnium0102030405060708090100110120130140150160170180190200210220230pmAtomic RadiusCovalent RadiusMetallic RadiusVan der Waals Radius

Chemical Properties

Energy
Proton Affinity
Electron Affinity
Ionization Energy
Ionization Energies of Hf (Hafnium)
Heat of Vaporization
Heat of Fusion
Heat of Formation
Electrons
Electron Shells2, 8, 18, 32, 10, 2
Bohr Model: Hf (Hafnium)
Valence Electrons2
Lewis Structure: Hf (Hafnium)
Electron Configuration[Xe] 4f14 5d2 6s2
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 4f14 5d2 6s2
Enhanced Bohr Model of Hf (Hafnium)
Orbital Diagram of Hf (Hafnium)
Oxidation States-2, 0, 1, 2, 3, 4
Electronegativity
1.3
Electrophilicity Index
States of Matter
PhaseSolid
Gas Phase
Boiling Point
Melting Point
Critical Pressure
Critical Temperature
Triple Point
Visual

Hafnium is a Gray. Hf has a CPK of #ff1493, Jmol of #4dc2ff, and MOLCAS GV of #4dc2ff. The Appearance of Element 72 is steel gray.

Color
Gray
Appearancesteel gray
Refractive Index
Thermodynamic Properties
Thermal Conductivity
Thermal Expansion
Molar Heat Capacity
Specific Heat Capacity
Heat Capacity Ratio (Adiabatic Index)
Electrical Properties
TypeConductor
Electrical Conductivity
Electrical Resistivity
Superconducting Point
Magnetism
Typeparamagnetic
Magnetic Susceptibility (Mass)
0.0000000053 m³/Kg
Magnetic Susceptibility (Molar)
0.000000000946 m³/mol
Magnetic Susceptibility (Volume)
0.0000705
Magnetic Ordering
Curie Point
Neel Point
Structure

The Crystal Structure of Hafnium is HEX. The lattice constant of Hf is 3.2 Å. The lattice angles of Element 72 are π/2, π/2, 2 π/3.

Crystal StructureSimple Hexagonal (HEX)
Lattice Constant
Lattice Anglesπ/2, π/2, 2 π/3
Mechanical Properties

Hafnium has a Brinell of 1700 MPa, Mohs hardness of 5.5 MPa, and Vickers of 1760 MPa. The Bulk Modulus of Hf is 110 GPa. The Shear Modulus of Element 72 is 30 GPa. The Young Modulus of Hafnium (Hf) is 78 GPa. The Poisson Ratio of Hafnium is 0.37. The Speed of Sound of Hf is 3010 m/s.

Hardness
Bulk Modulus
Shear Modulus
Young's Modulus
Poisson Ratio
0.37
Speed of Sound
Classification

The CAS Group of Hafnium is IVA. The IUPAC Group of Hf is IVB. The Glawe Number of Element 72 is 50. The Mendeleev Number of Hafnium (Hf) is 45. The Pettifor Number of Hafnium is 50. The Geochemical Class of Hf is high field strength. The Goldschmidt Class of Element 72 is litophile.

CategoryTransition metals, Transition metals
CAS GroupIVA
IUPAC GroupIVB
Glawe Number50
Mendeleev Number45
Pettifor Number50
Geochemical Classhigh field strength
Goldschmidt Classlitophile

Other

The Dipole Polarizability of Hafnium is 103 plus or minus 6 a₀. Hf has a C6 Dispersion Coefficient (GB) of 1040 a₀. The Allotropes of Element 72 is . The Neutron Cross Section of Hafnium (Hf) is 104. The Neutron Mass Absorption of Hafnium is 0.02. The Quantum Numbers of Hf is 3F2. The Space Group of Element 72 is 194 (P63/mmc).

Gas Basicity
Dipole Polarizability
C6 Dispersion Coefficient
Allotropes
Neutron Cross Section
104
Neutron Mass Absorption
0.02
Quantum Numbers3F2
Space Group194 (P63/mmc)

Isotopes of Hafnium

Stable Isotopes5
Unstable Isotopes33
Natural Isotopes6
Isotopic Composition18035.08%18035.08%17827.28%17827.28%17718.60%17718.60%17913.62%17913.62%1765.26%1765.26%1740.16%1740.16%

153Hf

Mass Number153
Neutron Number81
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
Spin1/2
Quadrupole Moment
0
Discovery Year2000
Parity+

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)

154Hf

Mass Number154
Neutron Number82
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
2 ± 1 s
Spin0
Quadrupole Moment
0
Discovery Year1981
Parity+

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%
α (α emission)0%

155Hf

Mass Number155
Neutron Number83
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
843 ± 30 ms
Spin7/2
Quadrupole Moment
Discovery Year1981
Parity-

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%
α (α emission)

156Hf

Mass Number156
Neutron Number84
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
23 ± 1 ms
Spin0
Quadrupole Moment
0
Discovery Year1979
Parity+

Decay ModeIntensity
α (α emission)100%
β+ (β+ decay; β+ = ϵ + e+)

157Hf

Mass Number157
Neutron Number85
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
115 ± 1 ms
Spin7/2
Quadrupole Moment
Discovery Year1965
Parity-

Decay ModeIntensity
α (α emission)94%
β+ (β+ decay; β+ = ϵ + e+)14%

158Hf

Mass Number158
Neutron Number86
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
2.85 ± 0.07 s
Spin0
Quadrupole Moment
0
Discovery Year1965
Parity+

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)55.7%
α (α emission)44.3%

159Hf

Mass Number159
Neutron Number87
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
5.2 ± 0.1 s
Spin7/2
Quadrupole Moment
Discovery Year1973
Parity-

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)65%
α (α emission)35%

160Hf

Mass Number160
Neutron Number88
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
13.6 ± 0.2 s
Spin0
Quadrupole Moment
0
Discovery Year1973
Parity+

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)99.3%
α (α emission)0.7%

161Hf

Mass Number161
Neutron Number89
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
18.4 ± 0.4 s
Spin7/2
Quadrupole Moment
Discovery Year1973
Parity-

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)99.71%
α (α emission)0.29%

162Hf

Mass Number162
Neutron Number90
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
39.4 ± 0.9 s
Spin0
Quadrupole Moment
0
Discovery Year1982
Parity+

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)99.992%
α (α emission)0.008%

163Hf

Mass Number163
Neutron Number91
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
40 ± 0.6 s
Spin5/2
Quadrupole Moment
Discovery Year1982
Parity-

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%
α (α emission)

164Hf

Mass Number164
Neutron Number92
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
111 ± 8 s
Spin0
Quadrupole Moment
0
Discovery Year1981
Parity+

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

165Hf

Mass Number165
Neutron Number93
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
76 ± 4 s
Spin5/2
Quadrupole Moment
Discovery Year1981
Parity-

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

166Hf

Mass Number166
Neutron Number94
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
6.77 ± 0.3 m
Spin0
Quadrupole Moment
0
Discovery Year1965
Parity+

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

167Hf

Mass Number167
Neutron Number95
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
2.05 ± 0.05 m
Spin5/2
Quadrupole Moment
Discovery Year1969
Parity

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

168Hf

Mass Number168
Neutron Number96
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
25.95 ± 0.2 m
Spin0
Quadrupole Moment
0
Discovery Year1961
Parity+

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%
ϵ (electron capture)98%
e+ (positron emission)2%

169Hf

Mass Number169
Neutron Number97
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
3.24 ± 0.04 m
Spin5/2
Quadrupole Moment
Discovery Year1969
Parity-

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

170Hf

Mass Number170
Neutron Number98
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
16.01 ± 0.13 h
Spin0
Quadrupole Moment
0
Discovery Year1961
Parity+

Decay ModeIntensity
ϵ (electron capture)100%

171Hf

Mass Number171
Neutron Number99
Relative Atomic Mass
G-Factor
-0.19257142857143 ± 0.0034285714285714
Abundance
Radioactivity☢️ Radioactive
Half Life
12.1 ± 0.4 h
Spin7/2
Quadrupole Moment
3.46 ± 0.03
Discovery Year1951
Parity+

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

172Hf

Mass Number172
Neutron Number100
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
1.87 ± 0.03 y
Spin0
Quadrupole Moment
0
Discovery Year1951
Parity+

Decay ModeIntensity
ϵ (electron capture)100%

173Hf

Mass Number173
Neutron Number101
Relative Atomic Mass
G-Factor
1.004 ± 0.014
Abundance
Radioactivity☢️ Radioactive
Half Life
23.6 ± 0.1 h
Spin1/2
Quadrupole Moment
0
Discovery Year1951
Parity-

Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

174Hf

Mass Number174
Neutron Number102
Relative Atomic Mass
G-Factor
0
Abundance
0.16 ± 0.12
Radioactivity☢️ Radioactive
Half Life
2 ± 0.4 Py
Spin0
Quadrupole Moment
0
Discovery Year1939
Parity+

Decay ModeIntensity
α (α emission)100%
+ (double β+ decay)

175Hf

Mass Number175
Neutron Number103
Relative Atomic Mass
G-Factor
-0.2708 ± 0.0036
Abundance
Radioactivity☢️ Radioactive
Half Life
70.65 ± 0.19 d
Spin5/2
Quadrupole Moment
2.72 ± 0.02
Discovery Year1949
Parity-

Decay ModeIntensity
ϵ (electron capture)100%

176Hf

Mass Number176
Neutron Number104
Relative Atomic Mass
G-Factor
0
Abundance
5.26 ± 0.7
RadioactivityStable
Half LifeNot Radioactive ☢️
Spin0
Quadrupole Moment
0
Discovery Year1934
Parity+

177Hf

Mass Number177
Neutron Number105
Relative Atomic Mass
G-Factor
0.226 ± 0.00025714285714286
Abundance
18.6 ± 0.16
RadioactivityStable
Half LifeNot Radioactive ☢️
Spin7/2
Quadrupole Moment
3.37 ± 0.03
Discovery Year1934
Parity-

178Hf

Mass Number178
Neutron Number106
Relative Atomic Mass
G-Factor
0
Abundance
27.28 ± 0.28
RadioactivityStable
Half LifeNot Radioactive ☢️
Spin0
Quadrupole Moment
0
Discovery Year1934
Parity+

179Hf

Mass Number179
Neutron Number107
Relative Atomic Mass
G-Factor
-0.14197777777778 ± 0.00031111111111111
Abundance
13.62 ± 0.11
RadioactivityStable
Half LifeNot Radioactive ☢️
Spin9/2
Quadrupole Moment
3.79 ± 0.03
Discovery Year1934
Parity+

180Hf

Mass Number180
Neutron Number108
Relative Atomic Mass
G-Factor
0
Abundance
35.08 ± 0.33
RadioactivityStable
Half LifeNot Radioactive ☢️
Spin0
Quadrupole Moment
0
Discovery Year1934
Parity+

181Hf

Mass Number181
Neutron Number109
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
42.39 ± 0.06 d
Spin1/2
Quadrupole Moment
0
Discovery Year1935
Parity-

Decay ModeIntensity
β (β decay)100%

182Hf

Mass Number182
Neutron Number110
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
8.9 ± 0.09 My
Spin0
Quadrupole Moment
0
Discovery Year1961
Parity+

Decay ModeIntensity
β (β decay)100%

183Hf

Mass Number183
Neutron Number111
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
1.018 ± 0.002 h
Spin3/2
Quadrupole Moment
Discovery Year1956
Parity-

Decay ModeIntensity
β (β decay)100%

184Hf

Mass Number184
Neutron Number112
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
4.12 ± 0.05 h
Spin0
Quadrupole Moment
0
Discovery Year1973
Parity+

Decay ModeIntensity
β (β decay)100%

185Hf

Mass Number185
Neutron Number113
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
3.5 ± 0.6 m
Spin9/2
Quadrupole Moment
Discovery Year1993
Parity-

Decay ModeIntensity
β (β decay)100%

186Hf

Mass Number186
Neutron Number114
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
2.6 ± 1.2 m
Spin0
Quadrupole Moment
0
Discovery Year1998
Parity+

Decay ModeIntensity
β (β decay)100%

187Hf

Mass Number187
Neutron Number115
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
Spin9/2
Quadrupole Moment
Discovery Year1999
Parity-

Decay ModeIntensity
β (β decay)

188Hf

Mass Number188
Neutron Number116
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
Spin0
Quadrupole Moment
0
Discovery Year1999
Parity+

Decay ModeIntensity
β (β decay)

189Hf

Mass Number189
Neutron Number117
Relative Atomic Mass
G-Factor
Abundance
Radioactivity☢️ Radioactive
Half Life
Spin3/2
Quadrupole Moment
Discovery Year2009
Parity-

Decay ModeIntensity
β (β decay)100%

190Hf

Mass Number190
Neutron Number118
Relative Atomic Mass
G-Factor
0
Abundance
Radioactivity☢️ Radioactive
Half Life
Spin0
Quadrupole Moment
0
Discovery Year2012
Parity+

Decay ModeIntensity
β (β decay)
Hf-crystal bar
Hafnium

History

In 1911, Georges Urbain claimed to have found the element in rare-earth residues which was shown later to be a mixture of already discovered lanthanides. Dirk Coster and George de Hevesy found it by X-ray spectroscopic analysis in Norwegian zircon in 1922. Anton Eduard van Arkel and Jan Hendrik de Boer were the first to prepare metallic hafnium by passing hafnium tetra-iodide vapor over a heated tungsten filament in 1924. From Hafinia, the Latin name for Copenhagen

DiscoverersDirk Coster, Georg von Hevesy
Discovery LocationDenmark
Discovery Year1923
Etymology (Name Origin)From Hafnia, the Latin name of Copenhagen.
PronunciationHAF-ni-em (English)
Hafnium is considered to be non-toxic
In powdered form, hafnium is pyrophoric and can ignite spontaneously in air

Uses

Hafnium oxide-based compounds are being introduced into silicon-based chips to produce smaller, more energy efficient and performance packed processors. Most of the hafnium produced is used in the production of control rods for nuclear reactors. Hafnium is also used in photographic flash bulbs, light bulb filaments, and in electronic equipment as cathodes and capacitors. Used in reactor control rods because of its ability to absorb neutrons.

Sources

Obtained from mineral zircon or baddeleyite.

Abundance
Abundance in Earth's crust
Natural Abundance (Oceans)
Natural Abundance (Human Body)
Natural Abundance (Meteor)
0.000017 %
Natural Abundance (Sun)
0.0000001 %
Abundance in Universe
0.00000007 %

Nuclear Screening Constants

1s1.3984
2p4.4012
2s18.8102
3d13.5702
3p21.0168
3s21.6885
4d36.476
4f39.7904
4p34.0704
4s33.0228
5d55.3805
5p52.415
5s50.167
6s62.8356

Also Known As

  • Hf
  • element 72
  • 72Hf

Translations

  • Norwegian Bokmålhafnium
  • Frenchhafnium
  • Italianafnio
  • Norwegian Nynorskhafnium
  • Danishhafnium
  • Swedishhafnium
  • GermanHafnium
  • Hungarianhafnium
  • Polishhafn
  • Afrikaanshafnium
  • Amharicሀፍኒየም
  • Aragonesehafnio
  • Arabicهافنيوم
  • Azerbaijanihafnium
  • Belarusianгафній
  • Bulgarianхафний
  • Banglaহ্যাফনিয়াম
  • Bretonhafniom
  • Bosnianhafnij
  • Catalanhafni
  • Corsicanafniu
  • Czechhafnium
  • Chuvashгафни
  • Welshhafniwm
  • Greekάφνιο
  • Esperantohafnio
  • Spanishhafnio
  • Estonianhafnium
  • Basquehafnio
  • Persianهافنیم
  • Finnishhafnium
  • Friulianafni
  • Irishhaifniam
  • Galicianhafnio
  • Manxhafnium
  • Hakka Chinesehafnium
  • Hebrewהפניום
  • Fiji HindiHafnium
  • Croatianhafnij
  • Armenianհաֆնիում
  • Interlinguahafnium
  • Indonesianhafnium
  • Idohafnio
  • Icelandichafnín
  • Japaneseハフニウム
  • Lojbanjinmrxafni
  • Javanesehafnium
  • Georgianჰაფნიუმი
  • Kazakhгафний
  • Korean하프늄
  • Kurdishhafniyûm
  • Komiгафний
  • Latinhafnium
  • LuxembourgishHafnium
  • Ligurianafnio
  • Lithuanianhafnis
  • Latvianhafnijs
  • Malayalamഹാഫ്നിയം
  • Marathiहाफ्नियम
  • Western Mariгафний
  • Malayhafnium
  • Low GermanHafnium
  • Dutchhafnium
  • OccitanAfni
  • Western Panjabiہافنیم
  • Portugueseháfnio
  • QuechuaHafniyu
  • Romanianhafniu
  • Russianгафний
  • Sicilianafniu
  • Serbo-CroatianHafnijum
  • Slovakhafnium
  • Slovenianhafnij
  • AlbanianHafniumi
  • Serbianхафнијум
  • Saterland FrisianHafnium
  • SwahiliHafni
  • Tamilஆஃபினியம்
  • Thaiแฮฟเนียม
  • Turkishhafniyum
  • Uyghurگافنىي
  • Ukrainianгафній
  • Urduہفنیئم
  • VepsGafnii
  • Vietnamesehafni
  • WarayHafnyo
  • KalmykГафниум
  • YorubaHafnium
  • Chinese
  • Cebuanohafnyo
  • Macedonianхафниум
  • Central Kurdishھافنیۆم
  • Odiaହାଫ୍‌ନିଅମ
  • Gujaratiહાફનીયમ
  • Punjabiਹਾਫ਼ਨੀਅਮ
  • TatarГафний
  • PiedmonteseAfnio
  • Scotshafnium
  • SomaliHaafniyaam
  • Cantonese
  • Belarusian (Taraskievica orthography)гафн
  • UzbekGafniy
  • Chinese (China)
  • Chinese (Simplified)
  • Chinese (Traditional)
  • Chinese (Hong Kong SAR China)
  • Chinese (Taiwan)
  • AromanianHafniu
  • Kannadaಹಾಫ್ನಿಯಮ್
  • Kyrgyzгафний
  • Limburgishhafnium
  • Sanskritहाफ्नियम
  • Hindiहाफ्नियम
  • Newariहाफ्नियम
  • Nepaliहाफ्नियम
  • Malteseħafnju
  • Lombardafnio
  • Scottish Gaelichafnium
  • Paliहाफ्नियम
  • Teluguహాఫ్నియం
  • cdohafnium
  • Min Nan ChineseHafnium
  • Bhojpuriहाफ्नियम
  • SundaneseHafnium
  • Asturianhafniu
  • Portuguese (Brazil)háfnio
  • Tajikгафний
  • Tibetanཧབ་ནིམ།
  • Literary Chinese
  • TagalogHapniyo
  • kbphafɩnɩyɔm
  • Mongolianгафни
  • Lingua Franca Novahafnio
  • Northern Frisianhafnium
  • oloGafnii
  • Volapükhafnin
  • Wu Chinese
  • SardinianÀfniu
  • Burmeseဟက်ဖ်နီယမ်
  • Moroccan Arabicهافنيوم
  • BashkirГафний
  • Pashtoهافنيوم
  • Egyptian Arabicهافنيوم
  • CornishHafniom
  • BalineseHafnium
  • KotavaXafnel
  • BikolHapnyo
  • Korean (North Korea)하프니움