Rhodium

Rhodium (Rh)

Rhodium is the 45th element in the periodic table and has a symbol of Rh and atomic number of 45. It has an atomic weight of 102.90550 and a mass number of 103. Rhodium has forty-five protons and fifty-eight neutrons in its nucleus, and forty-five electrons in five shells. It is located in group nine, period five and block d of the periodic table. Silvery white metallic transition element. Found with platinum and used in some platinum alloys. Not attacked by acids, dissolves only in aqua regia. Discovered in 1803 by W.H. Wollaston.
Atomic Number45
Atomic Weight102.9055
Mass Number103
Group9
Period5
Blockd
Protons45 p+
Neutrons58 n0
Electrons45 e-
Animated Bohr Model of Rh (Rhodium)

Properties

Physical Properties
Atomic Radius
135 pm
Molar Volume
Covalent Radius
125 pm
Metallic Radius
125 pm
Ionic Radius
66.5 pm
Crystal Radius
80.5 pm
Van der Waals Radius
210 pm
Density
12.4 g/cm³
Energy
Proton Affinity
768 kJ/mol
Electron Affinity
Ionization Energy
Ionization Energies of Rh (Rhodium)
Heat of Vaporization
494 kJ/mol
Heat of Fusion
21.8 kJ/mol
Heat of Formation
556 kJ/mol
Electrons
Electron Shells2, 8, 18, 16, 1
Bohr Model: Rh (Rhodium)
Valence Electrons1
Electron Configuration[Kr] 4d8 5s1
Enhanced Bohr Model of Rh (Rhodium)
Orbital Diagram of Rh (Rhodium)
Oxidation States-3, -1, 0, 1, 2, 3, 4, 5, 6, 7
Electronegativity
2.28
Electrophilicity
1.4609827901817496 eV/particle
Phases
PhaseSolid
Gas Phase
Boiling Point
3,968.15 K
Melting Point
2,236.15 K
Critical Pressure
Critical Temperature
Triple Point
Visual

Rhodium is a Silver. Rh has a CPK of #ff1493, Jmol of #0a7d8c, and MOLCAS GV of #0a7d8c. The Appearance of Element 45 is silvery white metallic.

Color
Silver
Appearancesilvery white metallic
Refractive Index
Thermodynamic Properties
Thermal Conductivity
Thermal Expansion
0.000008 1/K
Molar Heat Capacity
24.98 J/(mol K)
Specific Heat Capacity
0.243 J/(g⋅K)
Heat Capacity Ratio (Adiabatic Index)
Electrical Properties
TypeConductor
Electrical Conductivity
23 MS/m
Electrical Resistivity
0.00000004300000000003 m Ω
Superconducting Point
Magnetism
Typeparamagnetic
Magnetic Susceptibility (Mass)
0.0000000136 m³/Kg
Magnetic Susceptibility (Molar)
0.0000000014 m³/mol
Magnetic Susceptibility (Volume)
0.0001693
Magnetic Ordering
Curie Point
Neel Point
Structure

The Crystal Structure of Rhodium is FCC. The lattice constant of Rh is 3.8 Å. The lattice angles of Element 45 are π/2, π/2, π/2.

Crystal StructureFace Centered Cubic (FCC)
Lattice Constant
3.8 Å
Lattice Anglesπ/2, π/2, π/2
Mechanical Properties

Rhodium has a Brinell of 1100 MPa, Mohs hardness of 6 MPa, and Vickers of 1246 MPa. The Bulk Modulus of Rh is 380 GPa. The Shear Modulus of Element 45 is 150 GPa. The Young Modulus of Rhodium (Rh) is 275 GPa. The Poisson Ratio of Rhodium is 0.26. The Speed of Sound of Rh is 4700 m/s.

Hardness
6 MPa
Bulk Modulus
380 GPa
Shear Modulus
150 GPa
Young Modulus
275 GPa
Poisson Ratio
0.26
Speed of Sound
4,700 m/s
Classification

The CAS Group of Rhodium is VIIIA. The IUPAC Group of Rh is VIII. The Glawe Number of Element 45 is 63. The Mendeleev Number of Rhodium (Rh) is 64. The Pettifor Number of Rhodium is 66. The Geochemical Class of Rh is noble metal. The Goldschmidt Class of Element 45 is siderophile.

CategoryTransition metals, Transition metals
CAS GroupVIIIA
IUPAC GroupVIII
Glawe Number63
Mendeleev Number64
Pettifor Number66
Geochemical Classnoble metal
Goldschmidt Classsiderophile
Other

The Gas Basicity of Rhodium is 745.4 kJ/mol. The Dipole Polarizability of Rh is 66 plus or minus 10 a₀. Element 45 has a C6 Dispersion Coefficient (GB) of 708 a₀. The Allotropes of Rhodium (Rh) is . The Neutron Cross Section of Rhodium is 145. The Neutron Mass Absorption of Rh is 0.063. The Quantum Numbers of Element 45 is 4F9/2. The Space Group of Rhodium (Rh) is 225 (Fm_3m).

Gas Basicity
745.4 kJ/mol
Dipole Polarizability
66 ± 10 a₀
C6 Dispersion Coefficient
Allotropes
Neutron Cross Section
145
Neutron Mass Absorption
0.063
Quantum Numbers4F9/2
Space Group225 (Fm_3m)

Isotopes of Rhodium

Stable Isotopes1
Unstable Isotopes40
Radioactive Isotopes39

88Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
87.960429 ± 0.000429 Da
Mass Number88
G-Factor
Half Life
Spin
Quadrupole Moment
Discovery Year
Parity

88Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)%

89Rh

Abundance
Relative Atomic Mass
88.950992 ± 0.000387 Da
Mass Number89
G-Factor
Half Life
Spin9/2
Quadrupole Moment
Discovery Year
Parity+

89Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)%
β+ p (β+-delayed proton emission)%
p (proton emission)%

90Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
89.944569 ± 0.000215 Da
Mass Number90
G-Factor
0
Half Life
29 ± 3 ms
Spin0
Quadrupole Moment
0
Discovery Year1994
Parity+

90Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%
β+ p (β+-delayed proton emission)0.7%

91Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
90.937123 ± 0.00032 Da
Mass Number91
G-Factor
Half Life
1.47 ± 0.22 s
Spin9/2
Quadrupole Moment
Discovery Year1994
Parity+

91Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%
β+ p (β+-delayed proton emission)1.3%

92Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
91.932367692 ± 0.0000047 Da
Mass Number92
G-Factor
Half Life
5.61 ± 0.08 s
Spin6
Quadrupole Moment
Discovery Year1994
Parity+

92Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%
β+ p (β+-delayed proton emission)2.05%

93Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
92.925912778 ± 0.000002821 Da
Mass Number93
G-Factor
Half Life
13.9 ± 1.6 s
Spin9/2
Quadrupole Moment
Discovery Year1994
Parity+

93Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

94Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
93.92173045 ± 0.000003627 Da
Mass Number94
G-Factor
Half Life
70.6 ± 0.6 s
Spin4
Quadrupole Moment
Discovery Year1979
Parity+

94Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%
β+ p (β+-delayed proton emission)1.8%

95Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
94.915897893 ± 0.000004171 Da
Mass Number95
G-Factor
Half Life
5.02 ± 0.1 m
Spin9/2
Quadrupole Moment
Discovery Year1967
Parity

95Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

96Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
95.914451705 ± 0.000010737 Da
Mass Number96
G-Factor
Half Life
9.9 ± 0.1 m
Spin6
Quadrupole Moment
Discovery Year1967
Parity+

96Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

97Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
96.911327872 ± 0.000038071 Da
Mass Number97
G-Factor
Half Life
30.7 ± 0.6 m
Spin9/2
Quadrupole Moment
Discovery Year1955
Parity+

97Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

98Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
97.910707734 ± 0.000012782 Da
Mass Number98
G-Factor
Half Life
8.72 ± 0.12 m
Spin2
Quadrupole Moment
Discovery Year1955
Parity

98Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

99Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
98.908121241 ± 0.000020881 Da
Mass Number99
G-Factor
Half Life
16.1 ± 0.2 d
Spin1/2
Quadrupole Moment
0
Discovery Year1952
Parity-

99Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%

100Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
99.908114147 ± 0.000019458 Da
Mass Number100
G-Factor
Half Life
20.8 ± 0.1 h
Spin1
Quadrupole Moment
Discovery Year1948
Parity-

100Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)100%
ϵ (electron capture)95.1%
e+ (positron emission)4.9%

101Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
100.906158903 ± 0.00000627 Da
Mass Number101
G-Factor
Half Life
4.07 ± 0.05 y
Spin1/2
Quadrupole Moment
0
Discovery Year1948
Parity-

101Rh Decay Modes
Decay ModeIntensity
ϵ (electron capture)100%

102Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
101.906834282 ± 0.00000688 Da
Mass Number102
G-Factor
0.25 ± 0.2
Half Life
207 ± 1.5 d
Spin2
Quadrupole Moment
Discovery Year1941
Parity-

102Rh Decay Modes
Decay ModeIntensity
β+ (β+ decay; β+ = ϵ + e+)78%
β (β decay)22%

103Rh

Abundance
100
Relative Atomic Mass
102.905494081 ± 0.00000247 Da
Mass Number103
G-Factor
Half Life
Spin1/2
Quadrupole Moment
0
Discovery Year1934
Parity-

104Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
103.906645309 ± 0.000002471 Da
Mass Number104
G-Factor
Half Life
42.3 ± 0.4 s
Spin1
Quadrupole Moment
Discovery Year1939
Parity+

104Rh Decay Modes
Decay ModeIntensity
β (β decay)99.55%
β+ (β+ decay; β+ = ϵ + e+)0.45%

105Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
104.905687787 ± 0.000002685 Da
Mass Number105
G-Factor
1.26 ± 0.014285714285714
Half Life
35.341 ± 0.019 h
Spin7/2
Quadrupole Moment
Discovery Year1945
Parity+

105Rh Decay Modes
Decay ModeIntensity
β (β decay)100%

106Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
105.907285879 ± 0.000005786 Da
Mass Number106
G-Factor
2.55 ± 0.03
Half Life
30.07 ± 0.35 s
Spin1
Quadrupole Moment
Discovery Year1947
Parity+

106Rh Decay Modes
Decay ModeIntensity
β (β decay)100%

107Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
106.906747975 ± 0.000012937 Da
Mass Number107
G-Factor
Half Life
21.7 ± 0.4 m
Spin7/2
Quadrupole Moment
Discovery Year1951
Parity+

107Rh Decay Modes
Decay ModeIntensity
β (β decay)100%

108Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
107.908715304 ± 0.000015026 Da
Mass Number108
G-Factor
Half Life
16.8 ± 0.5 s
Spin1
Quadrupole Moment
Discovery Year1955
Parity+

108Rh Decay Modes
Decay ModeIntensity
β (β decay)100%

109Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
108.908749555 ± 0.000004336 Da
Mass Number109
G-Factor
Half Life
80.8 ± 0.7 s
Spin7/2
Quadrupole Moment
Discovery Year1972
Parity+

109Rh Decay Modes
Decay ModeIntensity
β (β decay)100%

110Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
109.911079745 ± 0.000019114 Da
Mass Number110
G-Factor
Half Life
3.35 ± 0.12 s
Spin1
Quadrupole Moment
Discovery Year1963
Parity+

110Rh Decay Modes
Decay ModeIntensity
β (β decay)100%

111Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
110.911643164 ± 0.000007356 Da
Mass Number111
G-Factor
Half Life
11 ± 1 s
Spin7/2
Quadrupole Moment
Discovery Year1975
Parity+

111Rh Decay Modes
Decay ModeIntensity
β (β decay)100%

112Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
111.914405199 ± 0.000047327 Da
Mass Number112
G-Factor
Half Life
3.4 ± 0.4 s
Spin1
Quadrupole Moment
Discovery Year1972
Parity+

112Rh Decay Modes
Decay ModeIntensity
β (β decay)100%

113Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
112.915440212 ± 0.000007656 Da
Mass Number113
G-Factor
Half Life
2.8 ± 0.12 s
Spin7/2
Quadrupole Moment
Discovery Year1971
Parity+

113Rh Decay Modes
Decay ModeIntensity
β (β decay)100%

114Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
113.91872168 ± 0.000076824 Da
Mass Number114
G-Factor
Half Life
1.85 ± 0.05 s
Spin1
Quadrupole Moment
Discovery Year1988
Parity+

114Rh Decay Modes
Decay ModeIntensity
β (β decay)100%

115Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
114.920311649 ± 0.000007857 Da
Mass Number115
G-Factor
Half Life
1.03 ± 3 s
Spin7/2
Quadrupole Moment
Discovery Year1988
Parity+

115Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)%

116Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
115.92406206 ± 0.000079261 Da
Mass Number116
G-Factor
Half Life
685 ± 39 ms
Spin1
Quadrupole Moment
Discovery Year1970
Parity+

116Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)2.1%

117Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
116.926036291 ± 0.000009548 Da
Mass Number117
G-Factor
Half Life
421 ± 30 ms
Spin7/2
Quadrupole Moment
Discovery Year1991
Parity+

117Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)7.6%

118Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
117.930341116 ± 0.000026018 Da
Mass Number118
G-Factor
Half Life
282 ± 9 ms
Spin1
Quadrupole Moment
Discovery Year1994
Parity+

118Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)3.1%

119Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
118.932556951 ± 0.00001 Da
Mass Number119
G-Factor
Half Life
190 ± 6 ms
Spin7/2
Quadrupole Moment
Discovery Year1994
Parity+

119Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)6.4%

120Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
119.937069 ± 0.000215 Da
Mass Number120
G-Factor
Half Life
129.6 ± 4.2 ms
Spin8
Quadrupole Moment
Discovery Year1994
Parity-

120Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)9.3%
2n (2-neutron emission)%

121Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
120.939613 ± 0.000665 Da
Mass Number121
G-Factor
Half Life
74 ± 4 ms
Spin7/2
Quadrupole Moment
Discovery Year1994
Parity+

121Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)11%

122Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
121.944305 ± 0.000322 Da
Mass Number122
G-Factor
Half Life
51 ± 6 ms
Spin7
Quadrupole Moment
Discovery Year1997
Parity-

122Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)3.9%
2n (2-neutron emission)%

123Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
122.947192 ± 0.000429 Da
Mass Number123
G-Factor
Half Life
42 ± 4 ms
Spin7/2
Quadrupole Moment
Discovery Year2010
Parity+

123Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)24%
2n (2-neutron emission)%

124Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
123.952002 ± 0.000429 Da
Mass Number124
G-Factor
Half Life
30 ± 2 ms
Spin2
Quadrupole Moment
Discovery Year2010
Parity+

124Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)31%
2n (2-neutron emission)%

125Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
124.955094 ± 0.000537 Da
Mass Number125
G-Factor
Half Life
26.5 ± 2 ms
Spin7/2
Quadrupole Moment
Discovery Year2010
Parity+

125Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)%
2n (2-neutron emission)%

126Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
125.960064 ± 0.000537 Da
Mass Number126
G-Factor
Half Life
19 ± 3 ms
Spin1
Quadrupole Moment
Discovery Year2010
Parity-

126Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)%
2n (2-neutron emission)%

127Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
126.963789 ± 0.000644 Da
Mass Number127
G-Factor
Half Life
28 ± 14 ms
Spin7/2
Quadrupole Moment
Discovery Year2015
Parity+

127Rh Decay Modes
Decay ModeIntensity
β (β decay)100%
β n (β-delayed neutron emission)%
2n (2-neutron emission)%

128Rh

AbundanceRadioactive ☢️
Relative Atomic Mass
127.970649 ± 0.000322 Da
Mass Number128
G-Factor
Half Life
Spin
Quadrupole Moment
Discovery Year2018
Parity

128Rh Decay Modes
Decay ModeIntensity
β (β decay)%
β n (β-delayed neutron emission)%
2n (2-neutron emission)%
Rhodium powder pressed melted

History

Rhodium was discovered in 1803 by William Hyde Wollaston in London. He used crude platinum ore presumably obtained from South America. The introduction of the three way catalytic converter by Volvo in 1976 increased the demand for rhodium. From the Greek word rhodon, rose

DiscoverersWilliam Wollaston
Discovery LocationEngland
Discovery Year1803
Etymology (Name Origin)Greek: rhodon (rose). Its salts give a rosy solution.
PronunciationRO-di-em (English)
Rhodium is considered to be non-toxic
Rhodium metal does not normally form an oxide, even when heated

Uses

The element's major use is as one of the catalysts in the three-way catalytic converters in automobiles. Rhodium is used as an alloying agent for hardening and improving the corrosion resistance of platinum and palladium. It is also used as a filter in mammography systems because of the characteristic X-rays it produces. Rhodium is also used for jewelry and for decorations. Used as a coating to prevent wear on high quality science equipment and with platinum to make thermocouples.

Sources

Obtained as a by-product of nickel production.

Abundance
Abundance in Earth's crust
0.001 mg/kg
Abundance in Oceans
Abundance in Human Body
Abundance in Meteor
0.000018 %
Abundance in Sun
0.0000002 %
Abundance in Universe
0.00000006 %

Nuclear Screening Constants

1s0.9244
2p4.0596
2s11.8454
3d14.595
3p16.8456
3s16.5615
4d31.5576
4p27.8604
4s26.4184
5s38.3605